Rainfall partitioning through a mixed cedar swamp and associated C and N fluxes in Southern Ontario,Canada     

Tim P. Duval 《水文研究》2019,33(11):1510-1524

Partitioning of rainfall through a forest canopy into throughfall, stemflow, and canopy interception is a critical process in the water cycle, and the contact of precipitation with vegetated surfaces leads to increased delivery of solutes to the forest floor. This study investigates the rainfall partitioning over a growing season through a temperate, riparian, mixed coniferous‐deciduous cedar swamp, an ecosystem not well studied with respect to this process. Seasonal throughfall, stemflow, and interception were 69.2%, 1.5%, and 29.3% of recorded above‐canopy precipitation, respectively. Event throughfall ranged from a low of 31.5 ± 6.8% for a small 0.8‐mm event to a high of 82.9 ± 2.4% for a large 42.7‐mm event. Rain fluxes of at least 8 mm were needed to generate stemflow from all instrumented trees. Most trees had funnelling ratios <1.0, with an exponential decrease in funnelling ratio with increasing tree size. Despite this, stand‐scale funnelling ratios averaged 2.81 ± 1.73, indicating equivalent depth of water delivered across the swamp floor by stemflow was greater than incident precipitation. Throughfall dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) averaged 26.60 ± 2.96 and 2.02 ± 0.16 mg L^?1, respectively, which were ~11 and three times above‐canopy rain levels. Stemflow DOC averaged 73.33 ± 7.43 mg L^?1, 35 times higher than precipitation, and TDN was 4.45 ± 0.56 mg L^?1, 7.5 times higher than rain. Stemflow DOC concentration was highest from Populus balsamifera and TDN greatest from Thuja occidentalis trees. Although total below‐canopy flux of TDN increased with increasing event size, DOC flux was greatest for events 20–30 mm, suggesting a canopy storage threshold of DOC was readily diluted. In addition to documenting rainfall partitioning in a novel ecosystem, this study demonstrates the excess carbon and nitrogen delivered to riparian swamps, suggesting the assimilative capacity of these zones may be underestimated.  相似文献   

Biogeochemistry of dissolved carbon,major, and trace elements during spring flood periods on the Ob River     

Sergey N. Vorobyev  Oleg S. Pokrovsky  Larisa G. Kolesnichenko  Rinat M. Manasypov  Liudmila S. Shirokova  Jan Karlsson  Sergey N. Kirpotin 《水文研究》2019,33(11):1579-1594

Detailed knowledge of the flood period of Arctic rivers remains one of the few factors impeding rigorous prediction of the effect of climate change on carbon and related element fluxes from the land to the Arctic Ocean. In order to test the temporal and spatial variability of element concentration in the Ob River (western Siberia) water during flood period and to quantify the contribution of spring flood period to the annual element export, we sampled the main channel year round in 2014–2017 for dissolved C, major, and trace element concentrations. We revealed high stability (approximately ≤10% relative variation) of dissolved C, major, and trace element concentrations in the Ob River during spring flood period over a 1‐km section of the river channel and over 3 days continuous monitoring (3‐hr frequency). We identified two groups of elements with contrasting relationship to discharge: (a) DIC and soluble elements (Cl, SO₄, Li, B, Na, Mg, Ca, P, V, Cr, Mn, As, Rb, Sr, Mo, Ba, W, and U) negatively correlated (p < 0.05) with discharge and exhibited minimal concentrations during spring flood and autumn high flow and (b) DOC and particle‐reactive elements (Al, Fe, Ti, Y, Zr, Nb, Cs, REEs, Hf, Tl, Pb, and Th), some nutrients (K), and metalloids (Ge, Sb, and Te), positively correlated (p < 0.05) with discharge and showed the highest concentrations during spring flood. We attribute the decreased concentration of soluble elements with discharge to dilution by groundwater feeding and increased concentration of DOC and particle‐reactive metals with discharge to leaching from surface soil, plant litter, and suspended particles. Overall, the present study provides first‐order assessment of fluxes of major and trace elements in the middle course of the Ob River, reveals their high temporal and spatial stability, and characterizes the mechanism of river water chemical composition acquisition.  相似文献   

基于DINEOF的静止海洋水色卫星数据重构方法研究          下载免费PDF全文

陈奕君  张丰  杜震洪  刘仁义 《海洋学研究》2019,37(4):14-23

静止轨道海洋水色成像仪(Geostationary Ocean Color Imager, GOCI)提供了时间分辨率达小时级的海洋水色数据,使得对海洋环境的逐时变化监测成为可能。然而受到海洋上空云、雾和霾的影响,数据出现连续高缺失率甚至完全缺失的情况,使得数据使用价值大大降低。在经验正交函数重构法(Data INterpolating Empirical Orthogonal Functions, DINEOF)的基础上,突出时间要素在重构中的地位,运用异常像元检测、拉普拉斯平滑滤波和时间模态2次分解插值,提出了适用于静止海洋水色卫星数据的重构方法——DINEOF-G。利用此方法对杭州湾2017年的GOCI总悬浮物质量浓度数据进行重构,结果表明该方法相比经典方法在重构精度上提高了8%,数据重构率提高了36%,且重构结果较好地反映了杭州湾总悬浮物质量浓度的季节变化规律和空间分布特征。  相似文献   

Prediction of depth‐integrated fluxes of suspended sediment in the Amazon River: particle aggregation as a complicating factor     

J. Bouchez  F. Métivier  M. Lupker  L. Maurice  M. Perez  J. Gaillardet  C. France‐Lanord 《水文研究》2011,25(5):778-794

Large rivers have been previously shown to be vertically heterogeneous in terms of suspended particulate matter (SPM) concentration, as a result of sorting of suspended solids. Therefore, the spatial distribution of suspended sediments within the river section has to be known to assess the riverine sedimentary flux. Numerous studies have focused on the vertical distribution of SPM in a river channel from a theoretical or experimental perspective, but only a few were conducted so far on very large rivers. Moreover, a technique for the prediction of depth‐integrated suspended sediment fluxes in very large rivers based on sediment transport dynamics has not yet been proposed. We sampled river water along depth following several vertical profiles, at four locations on the Amazon River and its main tributaries and at two distinct water stages. Depending on the vertical profile, a one‐ to fivefold increase in SPM concentration is observed from river channel surface to bottom, which has a significant impact on the ‘depth‐averaged’ SPM concentration. For each cross section, a so‐called Rouse profile quantitatively accounts for the trend of SPM concentration increase with depth, and a representative Rouse number can be measured for each cross section. However, the prediction of this Rouse number would require the knowledge of the settling velocity of particles, which is dependent on the state of aggregation affecting particles within the river. We demonstrate that in the Amazon River, particle aggregation significantly influences the Rouse number and renders its determination impossible from grain‐size distribution data obtained in the lab. However, in each cross section, the Rouse profile obtained from the fit of the data can serve as a basis to model, at first order, the SPM concentration at any position in the river cross section. This approach, combined with acoustic Doppler current profiler (ADCP) water velocity transects, allows us to accurately estimate the depth‐integrated instantaneous sediment flux. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Changes in dissolved organic matter (DOM) amount and composition along nested headwater stream locations during baseflow and stormflow          下载免费PDF全文

Shatrughan Singh  Shreeram Inamdar  Myron Mitchell 《水文研究》2015,29(6):1505-1520

Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter          下载免费PDF全文

R. J. Cooper  B. G. Rawlins  B. Lézé  T. Krueger  K. M. Hiscock 《水文研究》2014,28(13):4042-4056

Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Al_dithionate, Al_oxalate, Fe_dithionate, and Fe_oxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系   总被引：1，自引：0，他引：1  

夏鹏  付勇  杨镇  郭川  黄金强  黄明勇 《地质学报》2020,94(3):947-956

通过矿物组分、主量元素、微量元素、碳氧同位素等特征，分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明，牛蹄塘组下段以硅质页岩为主，TOC含量4. 96%~10. 10%；上段以富泥硅质页岩为主，TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境，沉积古水体为贫氧的还原状态；上段富泥硅质页岩沉积时期，仍为贫氧的还原环境，但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素，热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。  相似文献   

川西高原地区岩石中硒的地球化学特征和影响因素   总被引：1，自引：0，他引：1  

杨妍萍  刘晓端  刘久臣  汤奇峰  孟拓  朱晓华 《岩矿测试》2020,39(1):115-126

川西高原土壤、水体等多种介质研究表明,该地区的硒含量偏低,天然土壤剖面硒为0.06～0.16μg/g,表层土壤中硒含量为0.075～0.204μg/g,沉积物中硒含量为0.069～0.310μg/g,地表水中硒含量为nd～0.096μg/L,地下水中硒含量为nd～0.058μg/L,均低于我国相应环境介质中硒的平均含量,影响到当地人体健康。本文采集川西高原地区80件岩石样品,同时采集6套岩心样品,这些样品主要以板岩、砂岩、灰岩和页岩为主。采用原子荧光光谱法(AFS)测定硒含量,研究川西高原阿坝地区岩石与岩心样品中硒的地球化学特征和低硒的影响因素。结果表明:岩石硒含量范围为0.030～0.282μg/g,平均值0.09μg/g,低于硒土壤背景值。不同类型岩石中的硒含量大小为:页岩灰岩板岩砂岩。岩石中硒含量在不同地区也表现出较大的差异:松潘阿坝壤塘马尔康九寨沟若尔盖红原,可能是受到岩石类型及有机质和地质环境的影响所致。岩心各剖面的硒含量最小值为0.02～0.07μg/g,最大值为0.21～0.34μg/g,平均值为0.06～0.17μg/g,各钻孔的硒含量明显低于硒的地壳丰度。本研究认为,硒的分布受地质环境、有机质、岩石致密性等条件限制,低硒的地质环境是导致岩石中的硒含量较低的最主要因素。  相似文献   

大连长兴岛海域疏浚区GF-1 WFV影像悬浮物遥感反演研究     

王林  陈艳拢  袁仲杰  赵建华  孟庆辉  赵素芳  王祥  王新新 《海洋技术学报》2019,38(1)

利用2017年8-9月期间大连长兴岛海域实测遥感反射率、悬浮物浓度及GF-1 WFV数据,研究了该区域悬浮物浓度的遥感反演算法,发现遥感反射率与悬浮物浓度的散点图存在两种不同的变化趋势,将2008-2015年期间辽东湾内其它海域的数据与长兴岛海域数据进行叠加后,可初步推断产生两种变化趋势的主要原因在于疏浚区与非疏浚区悬浮物的粒径大小不同,导致其光学特性和反演算法也存在差异。将两种算法分别应用于2017年9月20日辽东湾及长兴岛近岸海域的GF-1 WFV4影像,发现采用非疏浚区算法反演长兴岛海域悬浮物浓度时,出现明显的低估现象,而疏浚区算法则能较好地反映出疏浚施工过程中悬浮物的分布规律,具有较好的工程应用价值。  相似文献